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MSDS

HPS Inc.
P.O. BOX 855
Rhome, TX 76078
U.S.A.

 
 
 

MSDS

LLA5000

  Page 1 of 6


Product Description: Material Safety Data Sheet
CLEAR-COATING
TYPE LLA5000 (AP1 – Aerosol Product)
UV-Protective Coating


Section 1: Manufacturer Identification

Formula # 30H003N12F
Company Phone Number: 262-251-6180
24 Hour Emergency: (800) 688-4005
Foreign Emergency: (01) (262) 236-8130 (USA

Date Printed: 04/07/06
Last Revision: 12/16/04

Manufactured to specifications for HPS, LLC.
Packaged for: (C2603)
HEMMI PAPILIO SUPPLIES LLC
NEWARK, TX 76071-3134


Section 2: Composition/Information on Ingredients
SARA 313 LISTED CARCINOGEN BY:
# Component CAS# % by WT. LISTED NTP IARC OSHA
1 METHYL ETHYL KETONE 78-93-3 30-36 Y N N N
2 ACETONE 67-64-1 20-26 N N N N
3 PROPANE 74-98-6 15-21 N N N N
4 PM ACETATE 108-65-6 5-8 N N N N
5 N-BUTANE 106-97-8 5-8 N N N N
6 ETHYL ESTER 763-69-9 3-5 N N N N
7 PLASTICIZER 85-68-7 1-3 Y N N N

Section 3: Hazards Identification

Emergency Overview: Danger! Extremely Flammable. Contents Under Pressure.

Appearance/Odor: Liquid Spray Mist/Solvent Odor

Potential Health Effects: See Section 11 for more information.


Likely Routes of Exposure: Eye contact, skin contact, ingestion, and inhalation Contact may cause redness, irritation, tearing, and blurred vision Contact may dry skin causing cracks and irritation
May be harmful if swallowed
Exposure to high concentrations of vapors may cause drowsiness, breathing difficulty, respiratory irritation, or headaches. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal.


Page 2 of 6

Product Description: Material Safety Data Sheet
CLEAR-COATING (APl - Aerosol Product)
TYPE LLA5000
UV-PROTECTIVE COATING

Medical Conditions Aggravated by Exposure:
Asthma and other respiratory ailments.
Target Organs: Kidney Liver Lung Brain

Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.

This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Section 4: First Aid Measures

Eye Contact: Immediately flush eyes with water for at least 15 minutes. If irritation develops get
medical attention.
Skin Contact: Remove contaminated clothing and wash before reuse. Wash skin with soap and water. Get
medical attention if irritation develops.
Inhalation: Move to fresh air. Contact emergency medical support if breathing stops or is irregular.

Ingestion: DO NOT induce vomiting. Get medical attention immediately.


Section 5: Fire Fighting Measures

Suitable Extinguishing Media: CO2 (Carbon Dioxide), dry chemical, or water fog. Unsuitable Extinguishing Media: Water spray may be unsuitable. However, if water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible explosion when exposed to extreme
heat.
Products of Combustion: These products are carbon oxides (CO,CO2).
Protection of Firefighters: Full protective equipment including self-contained breathing apparatus should be used.

section 6: Accidental Release Measures

Personal Precautions: Use personal protection recommended in Section 8.
Environmental Precautions: None known.





Page 3 of 6

Product Description: Material Safety Data Sheet
CLEAR-COATING (APl - Aerosol Product)
TYPE LLA5000 UV-PROTECTIVE COATING



Methods of Containment: Absorb spilled liquid in suitable material.
Methods of Clean-up: Use spark-proof tools to sweep or scrape up and containerize.
Other Information: Ventilate the area.

Section 7: Handling and Storage

Handling:
Vapors may ignite explosively. Prevent buildup of vapors; use with adequate ventilation. Keep from sparks, heat, flame or other heat sources. Do not smoke. Turn off pilot lights, heaters, electric motors and other sources of ignition during use and until all vapors are gone. Do not puncture or incinerate (burn) container.

Storage:
Store in dry well ventilated areas. above 48 degrees C (120 degrees F).

Do not expose to heat or store at temperatures

Section 8: Exposure Controls/Personal Protection

Exposure Guidelines

# COMPONENT ACGIH TLV-STEL ACGIH TLV-TWA OSHA PEL-TWA
1 METHYL ETHYL KETONE 300 ppm 200 ppm 200 ppm
2 ACETONE 750 ppm 500 ppm 1000 ppm
3 PROPANE 1800 ppm 2500 ppm 1000 ppm
4 PM ACETATE N/E ppm N/E ppm N/E ppm
5 N-BUTANE N/E 800 ppm 800 ppm
6 ETHYL ESTER 100 ppm 50 ppm 50 ppm
7 PLASTICIZER N/E ppm 5 ppm 5 ppm

Engineering Controls: Not generally required if product is applied in small quanti¬ties. If product is applied in larger quantities, provide ventilation to keep air contamination below OSHA permissible exposure limits and ACGIH TLV exposure levels.

Eye/face Protection: Wear safety glasses with side shields. Have eye wash facilities immediately available.


Skin Protection: Chemical resistant gloves if contact is likely.


Page 4 of 6

Product Description: Material Safety Data Sheet
CLEAR-COATING (API - Aerosol Product)
TYPE LLA5000
UV-PROTECTIVE COATING


Respiratory Protection: Use NIOSH-approved air-purifying respirator with organic cartridge or canister if exposure cannot be controlled within applicable limits with ventilation.

General Hygiene Considerations: Wash thoroughly after handling.

Section 9: Physical and Chemical Properties

Color: see product description
Odor: Solvent Odor
Physical State: Aerosol - Pressurized Liquid Freezing Point: Not Established (mixture) Boiling Range: <-18 C to 177 C «0 F to 350 F)
Flash Point: <-18 C «0 F)
Evaporation Rate: Faste_ than ether
Upper Flammability Limit: Not Established (mixture) Lower Flammability Limit: Not Established (mixture) Vapor Pressure: Approximately 50 psig @ 10 C (70 F) Specific Gravity: 0.748 @15 C (60 F)
Solubility (water): Negligible Percent Volatile, wt. %: 89.8
VOC Percent (CA): 67.9
MIR Number (CA): 1.198
Coating Category (CA): CLEAR COATING

Section 10: Stability and Reactivity

Stability: Stable under normal conditions.

Conditions to Avoid: Keep away from heat, sparks, and flames.

Incompatible Materials: Strong oxidizing agents.

Hazardous Decomposition Products: by fire - Carbon Dioxide and Carbon Monoxide

Possibility of Hazardous Reactions: Will not occur.




Page 5 of 6

Product Description: Material Safety Data Sheet
CLEAR-COATING (APl - Aerosol Product)
TYPE LLA5000
UV-PROTECTIVE COATING


Section 11: Toxicological Information

# COMPONENT LDSO Oral LDSO Dermal
1 METHYL ETHYL KETONE 200 mg/kg 590 mg/kg
2 ACETONE 1000 mg/kg 2400 mg/kg
3 PROPANE 1000 mg/kg 1800 mg/kg
4 PM ACETATE 8535 mg/kg 5000 mg/kg
5 N-BUTANE N/E N/E
6 ETHYL ESTER N/E N/E
7 PLASTICIZER 20400 mg/kg 10000 mg/kg
See Section 3 for other acute effect information.

Chronic Effects: Prolonged over-exposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Reports have associated the repeated and prolonged occupational OVER¬EXPOSURE to solvents with brain and nervous system damage. The deliberate misuse by concentrating and inhaling the vapors may be harmful or fatal. Carcinogenicity: See Section 2 for additional information.

Section 12: Ecological Information

No data available.

Section 13: Disposal Considerations

Do not puncture, incinerate or place container in trash compactor. Dispose of product in accordance with Federal, State, and Local regulations. Empty containers are 95% steel; recycle where allowed.




Page 6 of 6

Product Description: Material Safety Data Sheet
CLEAR-COATING (APl - Aerosol Product)
TYPE LLA5000
UV-PROTECTIVE COATING


Section 14: Transportation Information

US DOT (Ground)
Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D

US DOT (Air)
Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D-AIR

lATA (Domestic Air)
CONSUMER COMMODITY, ID 8000, CLASS 9, MISCELLANEOUS LABEL, Packing Instruction: 910.

lATA (International Air)
Proper Shipping Name: AEROSOLS, FLAMMABLE, N.O.S.; Class: 2.1; UN1950; Packing Instruction: Y203; Authorization: LTD. QTY.; FLAMMABLE GAS label required on box.

IMDG (Water)
Proper Shipping Name: AEROSOL PRODUCT, LTD QTY, IMDG Class 2, Page 2102, UN1950, Packing Group II, Marine Pollutant: Yes.

Section 15: Regulatory Information

International Chemical Inventory
TSCA: United States The components of this product are listed on the TSCA inventory.
DSL/NDSL: Canada The components of this product are listed on the DSL inventory.
AICS: Australia The components of this product are listed on the AICS inventory.

Section 313 Toxic Chemicals
See section 2. Chemicals marked with a "Y" are subject to the
SARA reporting requirements under 40 cfr 372.45(c) (5).

*California Safe Drinking Water and Toxic Enforcement Act of 1986 (proposition 65)
This product contains chemicals known to the state of California to cause cancer
and birth defects or other reproductive harm.

Section 16: Other Information

HMIS: Hazardous Material Identification System

Health – 2 Fire – 4 Reactivity - 1

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

This MSDS is based on information believed to be reliable and accurate. Because of changing reporting requirements and other variables it is impossible to guarantee
the accuracy of the information contained in this document. It is the responsibility of the user to determine proper personal protection based on the actual condition of use and to comply with all Federal, State and Local laws and regulations.
 

 
 
 

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